Benner
   
Karrar Abd Ali Al-Ameed ( Assistant Lecturer )
College Science - Chemistry
[email protected]
 
 
 
A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand
Download
Type:
General Speciality:
Logesh Mathivathanan Author Name:
,Karrar Al-Ameed, Katerina Lazarou, Zdeněk Trávníček Yiannis Sanakis, Radovan Herchel, John E. McGrady and Raphael G. Raptis Co Authors Names:
Dalton Transactions Publisher Name:
Royal Society of Chemistry  
2015 Publication Year:

Abstract

The encapsulation of a fluoride ion in a trigonal prismatic CuII6-pyrazolato cage results in a small expansion of the Cu6-host. The structural, electronic and magnetic features of the Cu6-complex, containing an endohedral fluoride in the rare μ6-F coordination mode, are compared with those of the parent complex with a vacant Cu6-cage.